Hmmm.....your sister, pfttt. Maybe she'll hit bottom some day, I'll pray.
Your mom....."hey Mom, I love you and hate that you are continually hurt by sis, but nothing changes if nothing changes. Please don't call me anymore to come and fix the mess that sis created because I can't keep doing it for my own health and sanity."
Be good to yourself, tell them you love them, remember that you can't keep rescuing someone who does NOT learn to stop throwing themselves under the bus!
Hugs and prayers,
HG